Grafite e grafene i materiali del futuro ? (1 Viewer)

PIZZODIGINO

Pacifico
Focus Graphite: The Company’s High-purity Graphite Deposit and Powerful, Next-generation Battery Products Can Extend EV Battery Performance by 65 Percent Giving it a Strong Market Advantage
Focus Graphite's Dr. Joseph Doninger discusses the company's graphite deposits and the advancements it has made in developing silicone-graphite anodes.
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Investing News Network • November 22, 2017

Joe-Doninger-3.jpg



Focus Graphite (TSXV:FMS,OTCQX:FCSMF,FWB:FKC) Director of Manufacturing and Technology Dr. Joseph Doninger is an internationally recognized expert in graphite-related processing technologies and manufacturing.

His developments culminated this year with the announcement of several technical achievements that significantly enhance the performance of next-generation lithium-ion batteries and alkaline batteries.

Here Dr. Joseph Doninger highlights the work done on the Lac Knife deposit, as well as engineering accomplishments that resulted in a line of superior-performing products vs. synthetic graphite and competing sources of natural flake graphite. Below is a transcript of the interview. It has been edited for clarity and brevity.


"Did you know graphite is as tough as diamonds, but its unique structure makes it light, soft, and highly resistant to heat as well?"


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Investing News Network: Please provide us with an overview of your background.

Focus Graphite Director of Technology and Manufacturing Dr. Joseph Doninger: I have a bachelor’s, master’s and doctor’s degree in chemical engineering from the universities of Illinois and Northwestern. I am also an honorary professor at the department of chemistry at the Kyiv National University of Technologies and Design.

As for my corporate background, I spent 20 years at International Minerals and Chemicals and then joined Superior Graphite as Vice President Technology in 1987. There I started focusing exclusively on graphite-related minerals, and retired from the company in 2004. After that, I formed my own consulting company and then joined Focus Graphite in 2012.

INN: How significant has the role of the Lac Knife graphite deposit been in developing the company’s battery minerals and products?

JD: Very significant. The Lac Knife deposit is very high in graphite content, ranging between 15 percent and 25 percent graphite. During our pilot plant tests we were able to confirm a low production cost of C$440 per tonne, which was reported in our feasibility study.

When extracting graphite there are impurities that need to be removed, and if the impurities lie within the flake, they are particularly difficult to remove. What is promising about the Lac Knife deposit is most of the impurities are on the surface of the flakes of graphite. The large +48 mesh flakes recovered during flotation had 98.8 percent carbon content, and after purification, the large-flake graphite reached a purity level of 99.98 percent carbon, which is ideal for batteries.

INN: Do the company’s achievements give Focus Graphite a clear advantage over other sources?

JD: Our initial advantage is that our resource is one of the best graphite sources that I’ve seen in natural graphite, and this is high-quality material that will play a role in batteries and other products.

The important thing we’ve proven is that the work we did in the pilot test is scalable and that the high purity of our Lac Knife graphite has a clear advantage in terms of long-term battery cycling performance in lithium-ion batteries.

INN: Are fine graphite flakes like those residing at Lac Knife commonly available to battery manufacturers from other mining developers?

JD: They are available, but most fine -200 mesh grades produced are relatively low in quality, with carbon levels of just 85 percent to 90 percent. We have demonstrated that our fine -200 mesh grade can be upgraded to as much as 95 percent carbon, making our sources from the Lac Knife deposit very competitive in terms of quality.

INN: Could you explain the benefits of superfine, ultrafine and expanded graphite and how they contribute to the development of lithium batteries?

JD: As a category, we introduced the superfine grade in March 2017 to the International Battery Seminar in Fort Lauderdale, Florida and it refers to the finest grade of spherical graphite. The benefit of this finer grade in the anode of lithium-ion batteries is that it will help accelerate the charging and discharging of batteries. This will play a significant role in electric vehicles, as it reduces the time needed to charge.

While spherical graphite is used in the anodes of batteries, ultrafine and expanded graphites are used as conductive additives in the cathode. The cathode is used to transfer electrons through active materials like lithium cobalt oxide and the non-conductive active materials like lithium, nickel, manganese and cobalt oxide. The graphite is added to improve the conductivity of the cathode mix and allows for electrons to travel in and out of the cathode during charging and discharging.

Expanded graphite is relatively new in the lithium-ion battery market, but has been used for quite some time in the alkaline market. Expanded Lac Knife graphite is five to 10 times more conductive than non-expanded Lac Knife graphite. The reason for this is that expanded graphite is produced by splitting the layers of graphite that comprise each flake into many individual thinner flakes that are more conductive than the original flake. This property means that less conductive graphite is required in the cathode, leaving more room for the active material and allowing for increased capacity in the battery.

INN: What is the significance of Focus Graphite’s recent development of a silicon-enhanced graphite anode?

JD: In lithium-ion batteries, graphite has a theoretical capacity of 372 amp hours per kilogram. On the other hand, for pure silicon, the theoretical capacity is more than 10 times higher. However, silicon is a costly material, and when it interacts with lithium it can swell up to four times its original size. This variability is not good for batteries as it makes them fail faster and reduces cycle life.

Combining the right amount of silicon with graphite in the proper way enables an increase in the reversible capacity while also preventing the material from expanding or contracting. We have found that adding 4.5 percent of silicon to graphite increases its theoretical capacity by 24 percent to 462 amp hours per kilogram.

INN: What does this mean for Focus Graphite moving forward. Do you anticipate even better performance results from additional development?

JD: At the EVS30 Symposium in Germany this year we reported on the work we had been doing with our Lac Knife graphite in batteries, including our ongoing work in developing silicon-enhanced graphite, where we added up to 18 percent of silicon, increasing the reversible capacity by 65 percent.

This showed that we can improve the capacity of batteries used in electric vehicles by an order of 50 percent to 65 percent, providing either higher power capabilities or added cycle life. We expect that silicon-enhanced graphites will play an important role in our success in the lithium-ion battery market moving forward.

INN: Do you see offtake agreements for graphite being introduced in the not-too-distant future?

JD: I believe that offtake agreements will make an appearance in the near future. With a growing demand for electric vehicles, the demand for sources of high-quality graphite is also growing. The graphite used in batteries is mostly coming from China; however, a number of Chinese producers are being shut down due to environmental regulations and a higher focus on quality. After all, lower-quality graphite leads to a much lower cycle life for batteries.

With this reduced supply and increased demand, I believe the trend will be to tie up high-grade sources of graphite from companies that have the technology to produce materials like silicon-enhanced spherical graphite for anodes in lithium-ion batteries and to modify high-purity graphite for use in battery cathodes. Focus Graphite is well positioned to offer a long-term supply of high-quality graphite.
 

PIZZODIGINO

Pacifico
Zenyatta Ventures Strengthens Team with the Addition of Brett Richards as Director and Chairman

Thunder Bay, ON

28 November 2017



Zenyatta Ventures Ltd. (“Zenyatta” or “Company”) (TSXV : ZEN) is pleased to announce the appointment of Brett A. Richards to the Board of Directors of Zenyatta where he will also act as Chairman.

Mr. Richards, who is based in London, England, is a well-respected mining industry executive with over 32 years of mining and metals business development experience. Brett has extensive mine project development, project financing, board and executive level experience on 5 continents in over 20 countries. He is currently the CEO of Midnight Sun Mining Corp. (TSXV:MMA), and has held executive management positions for private equity shareholders in the past including: CEO, African Thunder Platinum; CEO, Renew Resources; and CEO, Octéa Limited. Brett is formerly the transition CEO of Roxgold (TSX:ROG) through a successful shareholder proxy battle; was CEO of Avocet Mining plc (LSE:AVM & AIM:AVM) from 2008 to 2012, and was part of the five (5) person start-up of Katanga Mining Limited (TSX:KAT) from 2005 to 2008. Brett’s other publicly listed experience was in senior executive positions with Kinross Gold (TSX:K/NYSE:KGC) and Co-Steel Inc. (TSX:CEI).

Brett has significant public and private Board and Board Committee experience both in Canada, United Kingdom, Norway and Johannesburg. Brett is a Fellow of the Institute of Directors in London; a member of Ontario Association of Certified Engineering Technologists and (O.A.C.E.T.T. - Mechanical Engineering); a member of the London Metals Exchange (LME) and a member of the Prospectors and Developers Association of Canada (P.D.A.C). He is currently the principal of Richards Enterprises Inc. (CI).

Brett Richards commented, "I am very pleased to join the Board of Zenyatta Ventures. It has become apparent to me that Zenyatta has created considerable value from global collaboration and development related to the Albany high purity carbon material for conversion to an exciting nanomaterial called graphene. I am looking forward to advancing both the Albany graphite deposit to production and development activities of graphene applications under ZEN-tech Materials.”

Aubrey Eveleigh, President & CEO of Zenyatta commented, "We are very pleased to add a highly respected and accomplished mining executive of Brett Richards caliber to our Board. Brett is a creative leader with vision, backed by deep technical knowledge and hands-on experience. He will add considerable strength to our Board as we transition through pre-feasibility and prepare for the upcoming full feasibility study. Mr. Richards, who has a considerable network in the industry, will assist us in our efforts to organize and meet business objectives for both Zenyatta Ventures Ltd. and ZEN-tech Materials Limited.”

In connection with the appointment of Brett Richards as Director and Chairman, he has been granted stock options to purchase up to 500,000 common shares in the capital of the Company. The options are exercisable at a price of $0.60 for a five year period. Zenyatta will also be granting 240,000 stock options to consultants of the Company at the same price. The grant of such options is subject to regulatory approval
 

PIZZODIGINO

Pacifico
Sweden Increases Focus on Improving Conditions for the Supply of Innovation-Critical Metals and Minerals
Published by Craig P at 7th December 2017
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Vancouver, Canada – Leading Edge Materials Corp. (“Leading Edge Materials”) or (the Company”) (TSXV:LEM) (OTCQB: LEMIF) is pleased to share the recent findings of an in depth study by the Swedish Agency for Growth Policy Analysis (Tillväxtanalys) on the role Sweden can play in a future supply chain for a range of high value critical raw materials including rare earth elements, lithium, graphite and tungsten.

Leading Edge Materials holds significant mining and exploration assets for such materials in Sweden, and is presently seeking a Swedish listing on the Nasdaq First North market to allow for an increased focus on the Nordic region (see press release dated 4th October 2017).

The report, commissioned by the Swedish government and entitled “Innovation-critical metals & minerals from extraction to final product – how can the state support their development?” provides a very positive view on the pivotal role Sweden can play a critical raw material supply chain from mining through to recycling. Release of the report coincided with an event in Stockholm hosted by the Swedish Minister for Enterprise, Mikael Damberg, who emphasized the enviable position of Sweden as an innovative high technology country with a very active resources industry.

The Growth Analysis report outlines the future needs for innovation-critical metals and minerals, and provides policy recommendations for the Swedish Government on how to best stimulate the development of an entire Swedish production chain from extraction to finished product. A copy of the report can be found at http://www.tillvaxtanalys.se/in-english/publications/reports/reports/2017-11-23-innovation-critical-metals–minerals-from-extraction-to-final-product—how-can-the-state-support-their-development.html.

Blair Way, President and CEO, stated “We commend the Swedish Government for taking a long-range view on the mining and minerals industries, recognizing that new materials in addition to current ones shall be mined and recovered in Sweden in the near future. Innovation critical metals and minerals are relatively small volume but high value markets, yet they underpin the development of very extensive value add supply chains in renewable energy generation, storage and conservation. Many of these materials are presently mined in an unsustainable way in other parts of the world, and Sweden is taking positive steps towards becoming a global leader in sustainable mining of these new materials.

Leading Edge Materials presently receives significant support from the Swedish Government through the agency Vinnova, which funds collaborative research between companies, universities, research institutes and public sector. The Company is pleased to advise of the initiation of a fourth government funded project entitled “Graphene Energy” which aims to apply graphene from the Company’s Woxna graphite facility to enhance the electrical conductivity and the mechanical strength of lithium ion battery anodes. Other project partners comprise 2D fab AB, VestaSi AB, Ångström Advanced Battery Centre (ÅABC), Uppsala University (UU) and Mid Sweden University (MIUN).

With the initiation of this latest project, the Company is now collaborating in four Swedish government or European Commission supported projects, demonstrating the broad spectrum of potential markets for Woxna graphite:

  1. Vinnova Graphene Energy Project – Announced December 6th 2017
  2. Vinnova High Purity Graphite Battery Project – Natural Swedish Graphite for Future Lithium Ion Batteries – Announced 16th October, 2017
  3. InnoEnergy Li Ion Battery Manufacturing Project – Announced 27th July 2017
  4. Vinnova Graphene Composite Project – Graphene Modified Composites for Long-Term and High-Temperature Applications – Announced 8th June, 2017
These projects focus on sustainable high value applications for Woxna graphite. They apply both proven technology, and introduce innovative research to improve all aspects of the materials.

Leading Edge Materials is fortunate to be working closely with the Ångström Advanced Battery Centre (“ÅABC”) at Uppsala University, headed by battery industry leader Professor Kristina Edström. The Company’s work with the ÅABC provides an excellent example of the crossover between mining and emerging technology as envisaged under the Growth Analysis report and shall potentially allow for a deep and valuable graphite supply chain to be established in Sweden, based on materials sustainably sourced from the Woxna graphite mine.
 

PIZZODIGINO

Pacifico
Northern Graphite Signs Technology Licensing Agreement with Hatch Ltd.

December 7, 2017 – Northern Graphite Corporation (“Northern” or the “Company”) (NGC:TSXV, NGPHF:OTCQX) announces that it has signed an exclusive agreement to license certain Intellectual Property (“IP”) from Hatch Ltd. (“Hatch”) for use in Northern’s proprietary natural graphite purification process. Hatch’s IP relates to the design, construction and operation of a special fluidized bed reactor that is a key component of Northern’s chlorine based process. Under the Agreement, Hatch will provide engineering, design and technical support services and equipment with respect to the core technology, and will share in any royalties/revenues earned by Northern through licensing the Company’s technology to third parties.

Graphite mine concentrates must be upgraded with a secondary purification process in order to be used in a number of value added markets, the largest being lithium ion batteries (“LiBs”). Graphite is the anode material in LiBs and there are no substitutes. LiB anode material must be purified to 99.95% and some specific impurities, such as Fe, must be less than 50ppm. Essentially all of this purification is done in China using the wet chemical approach which is largely based on the use of hydrofluoric acid. This is difficult and/or expensive to do in the west because of environmental and workplace health and safety concerns. As the electric vehicle market expands and the demand for LiB anode material grows exponentially, it is critical that the west develop an alternative to current graphite purification processes.

Gregory Bowes, Chief Executive Officer, commented that; “Hatch’s know how, expertise and IP has facilitated the development of a cost competitive and environmentally sustainable solution to the purification problem.” He added; “Northern’s technology provides the opportunity to build and/or license anode material manufacturing plants in the west, in parallel with the development of our Bissett Creek graphite deposit.”

Northern’s proprietary purification technology will use a specially constructed continuous, fluidized bed reactor designed by Hatch. Northern’s process has been extensively tested in the lab and at a bench scale and the next step is to build a pilot plant to further evaluate its performance and refine capital and operating costs.

About Northern Graphite
Northern is a Canadian company with a 100% interest in the Bissett Creek graphite deposit located in southern Canada, relatively close to all required infrastructure. Bissett Creek is an advanced stage project that has a Full Feasibility Study and major environmental permit. Subject to the completion of operational and species at risk permitting, which are well advanced, Northern could commence construction 2018 pending financing. The Company believes Bissett Creek has the highest margin, best flake size distribution and lowest marketing risk of any new graphite project, and has the added advantages of low capital costs and realistic production levels relative to the size of the market.
 

PIZZODIGINO

Pacifico
Il caro grafite penalizza l'acciaio
La mancanza di materia prima e l'incremento della domanda extra siderurgica mettono sotto pressione gli elettrodi
21 luglio 2017 Versione stampabile


L’aumento relativamente marcato del prezzo degli elettrodi sta creando seri problemi ai produttori di acciaio con forno elettrico. L’industria degli elettrodi di grafite è legata strutturalmente a quella del settore dell’acciaio, poiché gli elettrodi sono utilizzati soprattutto dall’elettrosiderurgia.

I volumi delle vendite di elettrodi hanno un andamento più o meno corrispondente a quello del volume di produzione dell’acciaio. Quest’ultima, dopo una riduzione nei primi anni della crisi, è ritornata sui livelli del 2008 a livello mondiale, mentre in Italia si è ridotta di circa il 15%.

Nello stesso periodo la produzione di acciaio con ciclo integrale è invece cresciuta del 35%. Nonostante la produzione di acciaio da forno elettrico non sia aumentata negli ultimi dieci anni, il prezzo degli elettrodi è invece cresciuto. La spiegazione di questo fenomeno va ricercata nelle dinamiche del mercato degli elettrodi di grafite.

Tale mercato è molto concorrenziale a causa della presenza di un elevato numero di fornitori a livello regionale, sebbene i grandi players siano soltanto cinque: Graftech International (USA), Graphite India (India), SGL Carbon (Germania), Showa Denko Carbon (USA) e Nippon Carbon (Giappone). Nell’Unione Europea i principali produttori di elettrodi di grafite sono SGL Carbon Gmbh e Tokai Erftcarbon Gmbh in Germania, Graftech Switzerland SA in Svizzera, Graftech Iberica S.L. in Spagna.

La quota di mercato di questi quattro gruppi nell’area dei 28 Paesi dell’UE si è ridotta dall’85% nel 2006 a meno del 60% nel 2016 a causa della crescente concorrenza dei produttori asiatici, cinesi in primis.

L’aumento delle esportazioni cinesi di elettrodi ha influito pesantemente sui margini dei fornitori nazionali e regionali operando una selezione degli operatori sul lato dell’offerta.

Sul versante della domanda, il consumo di elettrodi, pur non essendo aumentato significativamente da parte del settore siderurgico, se si escludono i Paesi emergenti, è invece cresciuto parecchio negli altri settori, che contano per il 63% sul mercato totale della grafite, mettendo sotto pressione la domanda della materia prima utilizzata per produrre gli elettrodi.

Per quanto riguarda quest’ultima, il principale produttore ed esportatore mondiale è la Cina, con una quota intorno al 70%. È evidente che avendo pressoché il monopolio della materia prima, la Cina tenda a favorire i produttori nazionali di elettrodi, alzando i prezzi della grafite destinata all’export.

A farne le spese sono i produttori di elettrodi delle altre aree mondiali sprovviste della suddetta materia prima e, alla fine, le imprese siderurgiche delle medesime aree. A ciò va aggiunto che l’applicazione di dazi antidumping nei confronti dei produttori di elettrodi dei Paesi asiatici non fa che aggravare la posizione delle imprese siderurgiche delle altre aree del pianeta.
 

PIZZODIGINO

Pacifico
allarme per il rincaro del prezzo degli elettrodi in grafite preoccupa i produttori italiani di acciaio da forno elettrico. «Sul mercato - spiega Giovanni Pasini, componente del Consiglio di amministrazione di Feralpi - i prezzi si sono raddoppiati, in alcuni casi triplicati. Il fenomeno inizia a essere preoccupante, c’è il rischio di dovere essere costretti a rallentare la produzione se la situazione dovesse peggiorare. Nessuno può dirsi tranquillo». Secondo quanto riferiscono i produttori, l’attuale situazione di mercato è legata alla decisione del Governo cinese di fermare la produzione di alcune impianti per problemi ambientali. La situazione di scarsità ha portato gli altri produttori a rincarare i prezzi. L’elettrodo è fondamentale per il processo di fusione, ma l’usura data dall’arco elettricocomporta la necessità di una frequente sostituzione della componente. «Si è scatenata la tempesta perfetta - spiega Massimiliano Burelli, ad di Acciai speciali Terni -: le chiusure in Cina si sono sommate alla difficile reperibilità di needle coke e all’attesa per l’esito dell’istruttoria antitrust sul merger tra due produttori come Sgl Carbon e Sdk. Non prevedo possibilità di riequilibrio per tutto l’anno prossimo: inevitabilmente questa situazione impatterà sui prezzi di vendita».

Federacciai ed Eurofer hanno aperto un dossier sulla situazione. L’obiettivo è sollevare un problema di oligopolio speculativo, e comunicare ai soci in maniera chiara che gli aumenti di prezzo del prodotto finito saranno uguali per tutti e derivanti da un problema di approvvigionamento, non da scelte di mercato».


Non solo Ilva nel futuro del preridotto
La siderurgia italiana, a differenza di quanto avviene nel resto dell’Europa e del mondo, è fortemente sbilanciata verso il tipo di produzione ad arco elettrico. Secondo i dati di Federacciai, dei 22 milioni di acciaio prodotti nel 2015 ben 17 milioni sono derivati da forno elettrico: anche nel 2015 l’Italia si è confermata il primo produttore europeo di acciaio colato da forno elettrico, sia in termini assoluti sia relativi.

In autunno ci si aspetta un allarme anche per la magnesite, vale a dire per i mattoni refrattari. Una situazione che impatta con le difficoltà di Sanac, principale produttore in Italia (ha una quota di mercato del 35%), oggi in amministrazione straordinaria nell’ambito della procedura Ilva e messo in vendita nelle scorse settimane. L’auspicio degli operatori è che nei prossimi mesi tutta la produzione a livello nazionale venga messa a disposizione, allo scopo di evitare ulteriori difficoltà ai produttori
 

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